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ISHS Acta Horticulturae 542: VII International Symposium on the Processing Tomato

THE ANTIOXIDANT ACTIVITY OF TOMATO. IV. EFFECTS OF STORAGE ON OXIDATIVE AND HEAT DAMAGE

Authors:   G. Giovanelli, V. Lavelli, C. Peri, E. Pagliarini, B. Zanoni, P. Petrone
Keywords:   5-hydroxymethyl-2-furfural, color, ascorbic acid, lycopene, β-carotene, polyphenols, antioxidant activity
Abstract:
Three commercial tomato products (tomato pulp, tomato puree, and tomato paste) were subjected to accelerated aging tests (3 months at 40°C) to evaluate the kinetics of variation of heat damage indexes (5-hydroxymethyl-2-furfural [HMF] and color [ΔE]) and oxidative damage indexes (lycopene, beta-carotene, ascorbic acid, total phenolics, antioxidant activity of hydrophilic and lipophilic fractions). Experimental data were processed to obtain rate constant values. HMF formation followed zero-order kinetics in tomato puree, and paste, and first-order kinetics in tomato pulp, to a final value of nearly 160, 200, and 495 mg/kg dw in tomato pulp, puree, and paste. Significant colour changes were only observed in tomato concentrate. Ascorbic acid decreased in all products according to pseudo-first-order kinetics, with a higher rate in tomato paste and puree. A slight increase in total phenolics was observed in all products during storage. Lycopene concentration was very stable in all products, whereas beta-carotene decreased at the same rate in all products, to a final 30–40% reduction. The antioxidant activity of the hydrophilic fraction decreased, to a final reduction of 35–40% in all samples. The antioxidant activity of the lipophilic fraction also decreased, although to a smaller extent, to a final reduction of about 30% in the three products. Reduction of antioxidant activity can be ascribed to the loss in ascorbic acid and beta-carotene.

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