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ISHS Acta Horticulturae 306: International Symposium on Medicinal and Aromatic Plants, XXIII IHC

DIASTEREOSELECTIVE PARTIAL SYNTHESIS OF INDOLIC SECOLOGANIN DERIVATIVES

Authors:   Á. Patthy, L.F. Szabó, B. Podányi, P. Tétényi
Abstract:
The coupling of secologanin derivatives with tryptamine as well as 2-oxo-2,3-dihydrotryptamine derivatives has been studied. Depending on N/b/-substituent and solvent, remarkable stereoselectivity could be obtained according to the diamond lattice model. The results can contribute to the interpretation of the biosynthesis of strictosidine and vincoside as well.

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